To obtain Manaphy on Pokémon Quetzal (v0.8.1), you must hatch 30 or more eggs. After that, make sure to have a team of 5 Water-type Pokémon from any generation. Once both conditions are met, head to Sootopolis City and use Dive in the dark area of the lake.
After diving, enter the small underwater chamber. When you exit, Manaphy will be waiting for you at level 30.
Then, to obtain Phione on Pokémon Quetzal, place Manaphy and a Ditto in the Day Care. After some time, they will produce an egg, and Phione will hatch from it.
You can see how to get it in this video.
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